PLANTECO has developed cost-effective technologies for addressing
perchlorate and explosives contamination problems in soil/sediment,
groundwater and surface water.
Effective Bioremediation Options For Perchlorate- and Explosives-Contaminated
Soils and Water
Rationale: The field data PLANTECO has obtained
and reviewed for most perchlorate-contaminated sites indicate that the
source of the perchlorate in groundwater and surface water is perchlorate-contaminated
soils. This situation occurs because perchlorate slowly leaches into
groundwater via infiltration water and runoff. Thus, the amount of perchlorate
in groundwater at many sites often tracks the amount of perchlorate
in the contaminated soils. Often, the highest perchlorate concentrations
in groundwater have been detected directly below or down gradient of
very highly contaminated soils. The highest perchlorate concentrations
in water have mostly been detected in groundwater.
There is immediate need for suitable treatment technologies for perchlorate-contaminated
soils, groundwater and surface water at a number of Superfund and RCRA
sites in the United States. Ongoing cleanup efforts are focused on contaminated
groundwater. In California, Nevada and Texas, fluidized bed reactors
are currently used to pump-and-treat perchlorate-contaminated groundwater.
Phytoremediation and in-situ bioremediation of groundwater are undergoing
field-testing at other sites. While this approach may be appropriate
for sites where only groundwater is contaminated with perchlorate, such
efforts may be costly, if the contaminated soils are not treated as
well. Treating perchlorate plumes in groundwater and surface water without
addressing the source areas (soils) cannot and should not be considered
as a cost-effective permanent remedy. If perchlorate in soils is ignored
and the groundwater beneath is treated, the contaminated soils will
continue to act as a source of further the groundwater contamination.
Groundwater security can only be guaranteed by treating both contaminated
soils and groundwater to ensure that the treatment is permanent.
Soils: PLANTECO has demonstrated that in-situ
bioremediation of perchlorate-contaminated soils can be achieved cost-effectively
by delivering suitable carbon/electron sources to stimulate rapid biodegradation
of perchlorate at different depths in vadose zone soils (Patent Pending).
No dig and hull is involved. Our R&D team has successfully tested
the efficacy of this innovative in-situ soil bioremediation approach
(called SAMNAS®) in the field. The demonstration study
confirmed that perchlorate-contaminated soils could be remediated in
less than one year. Our team has developed quick screen test to obtain
design parameters for different types of soils and sediment (Ref: Hazardous
Waste Consultant, Volume 21, Issue 6, 2003 - see
article in pdf format). Under suitable field conditions, phytoremediation
can be coupled with SAMNAS® to remediate a multitude
of organic and inorganic contaminants in soils and groundwater simultaneously.
View a short video showing
the decrease of perchlorate in soils during an 8 month demonstration
of SAMNAS® st the Longhorn Army Ammunition Plant in Karnack,
TX. Perchlorate was not detected in followup samples collected at this
site 12 months later.
Groundwater: PLANTECO’s R&D team
pioneered the use of plants to remediate perchlorate-contaminated groundwater
(phytoremediation). Pilot testing of phytoremediation is underway at
field sites in California and Texas. PLANTECO’s R&D team has
recently shown that phytoremediation of co-contaminants consisting of
chlorinated solvents and perchlorate is feasible. PLANTECO has engineered
the root zone of woody plants to enhance rapid rhizodegradation and
minimize uptake of the contaminants by plants.
The in-situ injection of suitable electron sources to stimulate biodegradation
of perchlorate in deep aquifers is another promising approach we have
demonstrated in laboratory studies.
Surface Water: Constructed wetlands and constructed
microbial mats have been shown to rapidly degrade perchlorate. In fact,
PLANTECO has shown that perchlorate is more rapidly biodegraded in constructed
wetland systems than with upland tree plantations. Microbial mats (a
consortia of cyanobacteria and related heterotrophic bacteria) are very
effective for the remediation of perchlorate-contaminated water, which
may also contain other pollutants. Biomats® reduce and
sequester redox sensitive metals (Ag, As, Ba, Cd, Co, Cr6+, Cs, Cu,
Fe, Mn, Ni, Pb, Sr, U6+, Zn) and metabolize organic compounds (TNT,
RDX, HMX, NDMA, chlorinated organics, pesticides and hydrocarbons).
Our constructed microbial mats (Biomats®) are available
in multiple forms (floating mats, immobilized mats on inert fiber or
in silica) to facilitate their use in different treatment system designs.
The advantage of Biomats® compared with other systems
using active microorganisms is the integration of photosynthetic bacteria
into the microbial consortium, creating a self-sustainable system with
minimal need for supplemental nutrition. Biomats® will
grow in both fresh and salt water, as well as in brine solutions. Biomats®
utilize nitrate, sulfate, phosphate, and trace metals present in these
waters as growth nutrients.
In Situ Bioremediation of Explosives: In
field studies, PLANTECO's SAMNAS® technology has been
shown to be effective for simultaneous in situ biormediation of perchlorate
and explosives (e.g., TNT and its metabolites). Based on the success
of SAMNAS®, we are offering a performance guranteed to
our clients using this technology to cleanup these contaminants.